I don’t think that’s the case. The v0.19.0 release notes say:
Instance Blocks for Users
Users can now block instances. Similar to community blocks, it means that any posts from communities which are hosted on that instance are hidden. However the block doesn’t affect users from the blocked instance, their posts and comments can still be seen normally in other communities.
The closest thing to Librewolf on Android is Mull. Keep in mind that some of the settings are different.